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MATERIAL SAFETY DATA SHEET
ECOREX ACCION EW
1. IDENTIFICATION OF THE PREPARATION AND THE COMPANY
Identification of the formulation
Product name:
ECOREX ACCION EW Type of biocide: Insecticide for flying and creeping insects. Type of formulation: Concentrated water based emulsion. HSE approval number: 8703 .
Use of the substance or preparation
Ecorex Accion EW is an insecticide for strictly professional use, in the Environmental and Food Industry.
Identification of the company
Company that places the product on the market:
08006 - BARCELONA Telephone: +34 902 109 114 Fax: +34 93 415 63 44 E-Mail:[email protected] Emergency telephone
+34 93 760 14 71 2. DANGER IDENTIFICATION
Classification according to D1999/45/UE (DPD)
Dangerous for environment.

Risk phrases
R20/22 Harmful by inhalation and if swallowed.
R36/38 Irritating to eyes and skin.
R43
May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Safety phrases
S2
Keep out of the reach of children. Keep away from food, drink and animal feeding stuffs. Do not breathe vapours. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets.
Classification according to Regulation (UE) 1272/2008 (CLP)

ATTENTION
Hazard statements
H302
Harmful if swallowed. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. Very toxic to aquatic life with long lasting effects. Rev.5 – February 2015 MATERIAL SAFETY DATA SHEET
ECOREX ACCION EW
Precautionary statements
P102
Keep out of reach of children. Do not breathe vapours. Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. Dispose of contents and container according to local regulations. 3. COMPOSITION/INFORMATION ON INGREDIENTS
Composition
Isothiazolones mixture Solvents and excipients
Dangerous components
CAS No.
CLASSIFICATION ACCORDING TO R1272/2008 (CLP) Acute tox. Cat. 4; Skin sens. Cat 1; Aquatic Acute Cat. 1; Aquatic Chronic Cat. 1. H302, H332, H317, H410. CLASSIFICATION ACCORDING TO D67/548/CEE (DSD) R20/22, R43, R50/53 CLASSIFICATION ACCORDING TO R1272/2008 (CLP) ISOTHIAZOLONES MIXTURE Acute Tox. Cat. 3; Skin sens Cat 1; Skin corr. Cat. 1B; Aquatic acute Cat. 1; Aquatic Chronic Cat. 1. H301, H311, H331, H314, H400, H410, H317 CLASSIFICATION ACCORDING TO D67/548/CEE (DSD) T, C, Xi, N R23/24/25, R34 R43 50/53 4. FIRST AID MEASURES
First aid measures
Remove the person from contaminated area. Remove stained or splashed clothing. Do not administer anything by
mouth. Let the patient rest. Maintain body temperature. After the inhalation: Control breathing, if necessary via artificial
respiration. If the patient is unconscious, lie him down on his side with his head in a lower position than the rest of his
body and semi bent knees. Take the patient to hospital, and if possible, always take the label or container with you. If
contact with skin wash skin with plenty of water and soap, without rubbing.
If contact with eyes wash eyes with plenty of water for at least 15 minutes. In case of ingestion, do not provoke vomiting.
Take the patient to hospital, and if possible, always take the label or container with you.
NEVER LEAVE THE PERSON UNATTENDED.
Therapeutic measures
In case of ingestion, digestive decontamination, according to consciousness. Administer an aqueous solution of activated
carbon and a saline cathartic of sodium sulphate. Symptomatic treatment.
5. FIRE- FIGHTING MEASURES
Combustibility
Correct means of extinguishing fire
In case of small fire: Dry chemical powder, Carbon Dioxide.
In case of important fire: Pulverized water or alcohol resistant foam (do not apply jet directly).
Special risks during the fire extinction
The combustion products may be toxic and /or irritant. Measures must be taken to prevent the polluted extinction agent
from filtering into the ground or spreading uncontrollably. CO, CO2, NOx, SOx, POx.
Fire protection equipment
Use autonomous respiratory equipment to protect against smoke and also wear protective clothing.
Rev.5 – February 2015 MATERIAL SAFETY DATA SHEET
ECOREX ACCION EW
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Secure adequate ventilation. Wear a suitable respiratory protection equipment.
Measures to protect the environment
Avoid contamination of drains, surface and subterranean water systems, as well as the ground.
Cleaning measures
Avoid spreading with the aid of sand, earth or diatomaceous earth, etc. Pick up he splitted material into hermetic
containers, specially marked. The recovered product must be disposed of according to local legislation.
7. HANDLING AND STORAGE
HANDLING
Avoid contact with eyes and skin.
STORAGE
Special storage instructions
Keep the recipient well closed. Store in a cool and properly ventilated place. Keep away from light and humidity.
Suitable packing material (s)
Polyethylene bottles.
Maximum storage temperature 35 ºC
Minimum storage temperature 5 ºC
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
EXPOSURE LIMITS VALUES
Maximum exposure limits for professionals: Not established.

EXPOSURE CONTROL
Professional exposure control
Respiratory protection Wear respiratory protection, with filter.
Hand protection
Use protective nitrile gloves. Eye protection
Safety glasses with side protection or facial protection. Skin protection
Use adequate protection equipment. Environmental exposure controls
The product must to be handled and stored according to local legislation. The product is very toxic to aquatic organisms,
can cause adverse long term effects on the environment.
9. PHYSICAL AND CHEMICAL PROPERTIES
General information
Appearance:
Information concerning health, safety and the environment
Ignition point:
Boiling point:
Solubility in water:
Explosive properties:
Distillation range:
Vapour pressure:
Relative density at 20 ºC :
1.02 – 1.05 g/ml. pH 2% solution:
Viscosity(20 r.p.m. T-E, 20 ºC):
Rev.5 – February 2015 MATERIAL SAFETY DATA SHEET
ECOREX ACCION EW
10. STABILITY AND REACTIVITY
Chemical stability
Stable under normal conditions. Conditions to avoid
Sensitive to light and humidity. Materials to avoid
Strong oxidizing agents, strong acids, strong bases. Hazardous decomposition products
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Oral
DL50 >4.500 mg/kg. DL50 >5.700 mg/kg. Inhalation
CL50 >9.500 mg/m3
DANGEROUS HEALTH EFFECTS
Eyes and Skin
Permethrin
Non irritating (rabbit). Isothiazolones mixture Has no caustic effect on skin and eyes.
LONG AND SHORT TERM CHRONIC EFFECTS
Sensitisation
Permethrin
Slightly sensitising (pigs) Isothiazolones mixture Possible sensitisation by skin contact. Carcinogenicity
Permethrin
Not carcinogenic (rats and mice). Isothiazolones mixture No data available. Mutagenicity
Permethrin
Isothiazolones mixture Not mutagenic (OECD 471/EPA 84-4 method) Reproductive toxicity
Permethrin
No teratogenic effects. Isothiazolones mixture Not teratogenic (EPA 83-3 a method). 12. ECOLOGICAL INFORMATION
Ecotoxicity
Very toxic to aquatic organisms. Mobility
The product is water miscible Persistence and degradability:
The product is biodegradable. The product does not cause bioaccumulation in aquatic organisms. 13. DISPOSAL CONSIDERATIONS
Product disposal
Observe clothing rules and protection measures. Moisten solid material carefully to prevent burning.
Use carbonated or soapy water to clean the floor and contaminated objects.
Do not dispose waste waters into drains or the environment. Cover the product with an absorbent material such as sand,
earth or diatomaceous earth to prevent spreading.
Very polluted ground layers should be removed, until a clean layer arises. Use a suitable security container to prevent
environmental contamination.
The product MUST NOT be disposed of into municipal sewer systems, drains or rivers.
The treatment and/or disposal must be carried out according to local legislation. The spilled product cannot be reused
and must be disposed of. IT must be disposed of at an authorised residual waste collecting point.
Container disposal
Empty containers must be disposed of by an authorised dealer.
"Final holders of residues from industrial and commercial containers, must keep them in the conditions established in
article 12 of the Spanish Containers and Residues from Containers Law 11/1997."
Rev.5 – February 2015 MATERIAL SAFETY DATA SHEET
ECOREX ACCION EW
14. TRANSPORT INFORMATION
Special considerations
Use unbreakable recipients, making sure that they are well secured and labelled according to the legislation.
Miscibility with water
UN number
Packing Group
Danger ID

Classification for the transport by rail/road RID/ADR:
Denomination: Liquid substance potentially dangerous for the environment, (Permethrin 23.5%, Isothiazolone mixture
0.2%).
Additional information: Low harmfulness insecticide
Limited quantities: LQ7
Marine pollutant.

Classification for transport by sea, code-IMDG:
Denomination: Liquid substance potentially dangerous for the environment, (Permethrin 23.5%, Isothiazolone mixture
0.2%).
Additional information: Low harmfulness insecticide

Classification for transport by air IACO/IATA:
Denomination: Liquid substance potentially dangerous for the environment, (Permethrin 23.5%, Isothiazolone mixture
0.2%).
Additional information: Low harmfulness insecticide
Not allowed for air transport.
15. REGULATORY INFORMATION
Applied regulations
This Material safety data sheet comply with Annex I – Requirements for the Material safety data sheets elaboration from
Regulation (EC) number 453/2010.
16. OTHER INFORMATION
Danger substances mentioned on section 3 but not corresponded with product danger classification.
Classification according with EU Directives UE 67/548/CEE o 1999/45/CE
R23/24/25
Toxic by inhalation, in contact with skin and if swallowed.
Clasificación de acuerdo con el Reglamento (CE) 1272/2008 [UE-GHS/CLP]
H301
Toxic if swallowed. Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Toxic if inhaled. Harmful if inhaled. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.
Recommended use
For strictly professional us in the environmental and food hygiene industries. Read the label carefully before using this
product. Do not mix with any other chemical product. Secure proper ventilation before entering into the room. Follow
instructions in order to prevent risks for health and the environment.
Food industry use
Do not apply Ecorex Accion EW near foodstuff.
Measures must be taken to prevent foodstuff, machines and tools handled in previously treated rooms from containing
Rev.5 – February 2015 MATERIAL SAFETY DATA SHEET
ECOREX ACCION EW
residues. Do not use in the presence of people. Method of application: located spraying of water dilution of the product into skirting board /ground. Do not spray over or apply on surfaces where foodstuff is handled, prepared, consumed or served. Environmental Use Do not use in the presence of people and/or pets. Do not spray over foodstuff or cooking tools. Mode of application: Spraying or nebulization of water dilution of the product. The information published here is based on the knowledge and good work of the safety data files of the Manufactures of raw Materials. Therefore, this cannot be interpreted as guarantee for any specific property of the product. As consequence, it is under the users exclusive responsibility to decide if the information provided is appropriate or useful. Rev.5 – February 2015

Source: http://pestwright.co.uk/wp-content/uploads/2011/09/Ecorex_Accion.pdf